A History of Science-3 [118]
making up a gas as if they could actually see and watch their individual actions. Through study of the viscosity of gases--that is to say, of the degree of frictional opposition they show to an object moving through them or to another current of gas--an idea was gained, with the aid of mathematics, of the rate of speed at which the particles of the gas are moving, and the number of collisions which each particle must experience in a given time, and of the length of the average free path traversed by the molecule between collisions, These measurements were confirmed by study of the rate of diffusion at which different gases mix together, and also by the rate of diffusion of heat through a gas, both these phenomena being chiefly due to the helter-skelter flight of the molecules.
It is sufficiently astonishing to be told that such measurements as these have been made at all, but the astonishment grows when one hears the results. It appears from Clerk-Maxwell's calculations that the mean free path, or distance traversed by the molecules between collisions in ordinary air, is about one-half-millionth of an inch; while the speed of the molecules is such that each one experiences about eight billions of collisions per second! It would be hard, perhaps, to cite an illustration showing the refinements of modern physics better than this; unless, indeed, one other result that followed directly from these calculations be considered such--the feat, namely, of measuring the size of the molecules themselves. Clausius was the first to point out how this might be done from a knowledge of the length of free path; and the calculations were made by Loschmidt in Germany and by Lord Kelvin in England, independently.
The work is purely mathematical, of course, but the results are regarded as unassailable; indeed, Lord Kelvin speaks of them as being absolutely demonstrative within certain limits of accuracy. This does not mean, however, that they show the exact dimensions of the molecule; it means an estimate of the limits of size within which the actual size of the molecule may lie. These limits, Lord Kelvin estimates, are about the one- ten-millionth of a centimetre for the maximum, and the one-one-hundred-millionth of a centimetre for the minimum. Such figures convey no particular meaning to our blunt senses, but Lord Kelvin has given a tangible illustration that aids the imagination to at least a vague comprehension of the unthinkable smallness of the molecule. He estimates that if a ball, say of water or glass, about "as large as a football, were to be magnified up to the size of the earth, each constituent molecule being magnified in the same proportion, the magnified structure would be more coarse-grained than a heap of shot, but probably less coarse-grained than a heap of footballs."
Several other methods have been employed to estimate the size of molecules. One of these is based upon the phenomena of contact electricity; another upon the wave-theory of light; and another upon capillary attraction, as shown in the tense film of a soap-bubble! No one of these methods gives results more definite than that due to the kinetic theory of gases, just outlined; but the important thing is that the results obtained by these different methods (all of them due to Lord Kelvin) agree with one another in fixing the dimensions of the molecule at somewhere about the limits already mentioned. We may feel very sure indeed, therefore, that the molecules of matter are not the unextended, formless points which Boscovich and his followers of the eighteenth century thought them. But all this, it must be borne in mind, refers to the molecule, not to the ultimate particle of matter, about which we shall have more to say in another connection. Curiously enough, we shall find that the latest theories as to the final term of the series are not so very far afield from the dreamings of the eighteenth-century philosophers; the electron of J. J. Thompson shows many points of resemblance to the formless centre of Boscovich.
Whatever the exact form of the molecule,
It is sufficiently astonishing to be told that such measurements as these have been made at all, but the astonishment grows when one hears the results. It appears from Clerk-Maxwell's calculations that the mean free path, or distance traversed by the molecules between collisions in ordinary air, is about one-half-millionth of an inch; while the speed of the molecules is such that each one experiences about eight billions of collisions per second! It would be hard, perhaps, to cite an illustration showing the refinements of modern physics better than this; unless, indeed, one other result that followed directly from these calculations be considered such--the feat, namely, of measuring the size of the molecules themselves. Clausius was the first to point out how this might be done from a knowledge of the length of free path; and the calculations were made by Loschmidt in Germany and by Lord Kelvin in England, independently.
The work is purely mathematical, of course, but the results are regarded as unassailable; indeed, Lord Kelvin speaks of them as being absolutely demonstrative within certain limits of accuracy. This does not mean, however, that they show the exact dimensions of the molecule; it means an estimate of the limits of size within which the actual size of the molecule may lie. These limits, Lord Kelvin estimates, are about the one- ten-millionth of a centimetre for the maximum, and the one-one-hundred-millionth of a centimetre for the minimum. Such figures convey no particular meaning to our blunt senses, but Lord Kelvin has given a tangible illustration that aids the imagination to at least a vague comprehension of the unthinkable smallness of the molecule. He estimates that if a ball, say of water or glass, about "as large as a football, were to be magnified up to the size of the earth, each constituent molecule being magnified in the same proportion, the magnified structure would be more coarse-grained than a heap of shot, but probably less coarse-grained than a heap of footballs."
Several other methods have been employed to estimate the size of molecules. One of these is based upon the phenomena of contact electricity; another upon the wave-theory of light; and another upon capillary attraction, as shown in the tense film of a soap-bubble! No one of these methods gives results more definite than that due to the kinetic theory of gases, just outlined; but the important thing is that the results obtained by these different methods (all of them due to Lord Kelvin) agree with one another in fixing the dimensions of the molecule at somewhere about the limits already mentioned. We may feel very sure indeed, therefore, that the molecules of matter are not the unextended, formless points which Boscovich and his followers of the eighteenth century thought them. But all this, it must be borne in mind, refers to the molecule, not to the ultimate particle of matter, about which we shall have more to say in another connection. Curiously enough, we shall find that the latest theories as to the final term of the series are not so very far afield from the dreamings of the eighteenth-century philosophers; the electron of J. J. Thompson shows many points of resemblance to the formless centre of Boscovich.
Whatever the exact form of the molecule,