A History of Science-3 [120]
colder surrounding medium, the molecules, giving off their excess of energy, become relatively quiescent, and at a certain stage the gas becomes a liquid. The exact point at which this transformation occurs, however, differs enormously for different substances. In the case of water, for example, it is a temperature more than four hundred degrees above zero, centigrade; while for atmospheric air it is one hundred and ninety-four degrees centigrade below zero, or more than a hundred and fifty degrees below the point at which mercury freezes.
Be it high or low, the temperature above which any substance is always a gas, regardless of pressure, is called the critical temperature, or absolute boiling- point, of that substance. It does not follow, however, that below this point the substance is necessarily a liquid. This is a matter that will be determined by external conditions of pressure. Even far below the critical temperature the molecules have an enormous degree of activity, and tend to fly asunder, maintaining what appears to be a gaseous, but what technically is called a vaporous, condition--the distinction being that pressure alone suffices to reduce the vapor to the liquid state. Thus water may change from the gaseous to the liquid state at four hundred degrees above zero, but under conditions of ordinary atmospheric pressure it does not do so until the temperature is lowered three hundred degrees further. Below four hundred degrees, however, it is technically a vapor, not a gas; but the sole difference, it will be understood, is in the degree of molecular activity.
It thus appeared that the prevalence of water in a vaporous and liquid rather than in a "permanently" gaseous condition here on the globe is a mere incident of telluric evolution. Equally incidental is the fact that the air we breathe is "permanently" gaseous and not liquid or solid, as it might be were the earth's surface temperature to be lowered to a degree which, in the larger view, may be regarded as trifling. Between the atmospheric temperature in tropical and in arctic regions there is often a variation of more than one hundred degrees; were the temperature reduced another hundred, the point would be reached at which oxygen gas becomes a vapor, and under increased pressure would be a liquid. Thirty-seven degrees more would bring us to the critical temperature of nitrogen.
Nor is this a mere theoretical assumption; it is a determination of experimental science, quite independent of theory. The physicist in the laboratory has produced artificial conditions of temperature enabling him to change the state of the most persistent gases. Some fifty years since, when the kinetic theory was in its infancy, Faraday liquefied carbonic-acid gas, among others, and the experiments thus inaugurated have been extended by numerous more recent investigators, notably by Cailletet in Switzerland, by Pictet in France, and by Dr. Thomas. Andrews and Professor James Dewar in England. In the course of these experiments not only has air been liquefied, but hydrogen also, the most subtle of gases; and it has been made more and more apparent that gas and liquid are, as Andrews long ago asserted, "only distant stages of a long series of continuous physical changes." Of course, if the temperature be lowered still further, the liquid becomes a solid; and this change also has been effected in the case of some of the most "permanent" gases, including air.
The degree of cold--that is, of absence of heat-- thus produced is enormous, relatively to anything of which we have experience in nature here at the earth now, yet the molecules of solidified air, for example, are not absolutely quiescent. In other words, they still have a temperature, though so very low. But it is clearly conceivable that a stage might be reached at which the molecules became absolutely quiescent, as regards either translational or vibratory motion. Such a heatless condition has been approached, but as yet not quite attained, in laboratory experiments. It is called the absolute zero of temperature,
Be it high or low, the temperature above which any substance is always a gas, regardless of pressure, is called the critical temperature, or absolute boiling- point, of that substance. It does not follow, however, that below this point the substance is necessarily a liquid. This is a matter that will be determined by external conditions of pressure. Even far below the critical temperature the molecules have an enormous degree of activity, and tend to fly asunder, maintaining what appears to be a gaseous, but what technically is called a vaporous, condition--the distinction being that pressure alone suffices to reduce the vapor to the liquid state. Thus water may change from the gaseous to the liquid state at four hundred degrees above zero, but under conditions of ordinary atmospheric pressure it does not do so until the temperature is lowered three hundred degrees further. Below four hundred degrees, however, it is technically a vapor, not a gas; but the sole difference, it will be understood, is in the degree of molecular activity.
It thus appeared that the prevalence of water in a vaporous and liquid rather than in a "permanently" gaseous condition here on the globe is a mere incident of telluric evolution. Equally incidental is the fact that the air we breathe is "permanently" gaseous and not liquid or solid, as it might be were the earth's surface temperature to be lowered to a degree which, in the larger view, may be regarded as trifling. Between the atmospheric temperature in tropical and in arctic regions there is often a variation of more than one hundred degrees; were the temperature reduced another hundred, the point would be reached at which oxygen gas becomes a vapor, and under increased pressure would be a liquid. Thirty-seven degrees more would bring us to the critical temperature of nitrogen.
Nor is this a mere theoretical assumption; it is a determination of experimental science, quite independent of theory. The physicist in the laboratory has produced artificial conditions of temperature enabling him to change the state of the most persistent gases. Some fifty years since, when the kinetic theory was in its infancy, Faraday liquefied carbonic-acid gas, among others, and the experiments thus inaugurated have been extended by numerous more recent investigators, notably by Cailletet in Switzerland, by Pictet in France, and by Dr. Thomas. Andrews and Professor James Dewar in England. In the course of these experiments not only has air been liquefied, but hydrogen also, the most subtle of gases; and it has been made more and more apparent that gas and liquid are, as Andrews long ago asserted, "only distant stages of a long series of continuous physical changes." Of course, if the temperature be lowered still further, the liquid becomes a solid; and this change also has been effected in the case of some of the most "permanent" gases, including air.
The degree of cold--that is, of absence of heat-- thus produced is enormous, relatively to anything of which we have experience in nature here at the earth now, yet the molecules of solidified air, for example, are not absolutely quiescent. In other words, they still have a temperature, though so very low. But it is clearly conceivable that a stage might be reached at which the molecules became absolutely quiescent, as regards either translational or vibratory motion. Such a heatless condition has been approached, but as yet not quite attained, in laboratory experiments. It is called the absolute zero of temperature,