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By Root 1873 0

book in itself, but I offer here this crisp summation by the chemist P. W. Atkins, just to provide a sense of them: “There are four Laws. The third of them, the Second Law, was recognized first; the first, the Zeroth Law, was formulated last; the First Law was second; the Third Law might not even be a law in the same sense as the others.” In briefest terms, the second law states that a little energy is always wasted. You can't have a perpetual motion device because no matter how efficient, it will always lose energy and eventually run down. The first law says that you can't create energy and the third that you can't reduce temperatures to absolute zero; there will always be some residual warmth. As Dennis Overbye notes, the three principal laws are sometimes expressed jocularly as (1) you can't win, (2) you can't break even, and (3) you can't get out of the game.

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*12The notable exception being the Tyrannosaurus rex, which was found by Barnum Brown in 1902.

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*13The confusion over the aluminum/aluminium spelling arose because of some uncharacteristic indecisiveness on Davy's part. When he first isolated the element in 1808, he called it alumium. For some reason he thought better of that and changed it to aluminum four years later. Americans dutifully adopted the new term, but many British users disliked aluminum, pointing out that it disrupted the -ium pattern established by sodium, calcium, and strontium, so they added a vowel and syllable.

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*14The principle led to the much later adoption of Avogadro’s number, a basic unit of measure in chemistry, which was named for Avogadro long after his death. It is the number of molecules found in 2.016 grams of hydrogen gas (or an equal volume of any other gas). Its value is placed at 6.0221367 x 1023, which is an enormously large number. Chemistry students have long amused themselves by computing just how large a number it is, so I can report that it is equivalent to the number of popcorn kernels needed to cover the United States to a depth of nine miles, or cupfuls of water in the Pacific Ocean, or soft drink cans that would, evenly stacked, cover the Earth to a depth of 200 miles. An equivalent number of American pennies would be enough to make every person on Earth a dollar trillionaire. It is a big number.

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*15Specifically it is a measure of randomness or disorder in a system. Darrell Ebbing, in the textbook General Chemistry, very usefully suggests thinking of a deck of cards. A new pack fresh out of the box, arranged by suit and in sequence from ace to king, can be said to be in its ordered state. Shuffle the cards and you put them in a disordered state. Entropy is a way of measuring just how disordered that state is and of determining the likelihood of particular outcomes with further shuffles. Of course, if you wish to have any observations published in a respectable journal you will need also to understand additional concepts such as thermal nonuniformities, lattice distances, and stoichiometric relationships, but that's the general idea.

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*16Planck was often unlucky in life. His beloved first wife died early, in 1909, and the younger of his two sons was killed in the First World War. He also had twin daughters whom he adored. One died giving birth. The surviving twin went to look after the baby and fell in love with her sister's husband. They married and two years later she died in childbirth. In 1944, when Planck was eighty-five, an Allied bomb fell on his house and he lost everything—papers, diaries, a lifetime of accumulations. The following year his surviving son was caught in a conspiracy to assassinate Hitler and executed.

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*17Einstein was honored, somewhat vaguely, “for services to theoretical physics.” He had to wait sixteen years, till 1921, to receive the award—quite a long time, all things considered, but nothing at all compared with Frederick Reines, who detected the neutrino in 1957 but wasn't honored with a Nobel until 1995, thirty-eight years later, or the