Absolutely Small - Michael D. Fayer [17]
The interferometer and the interference pattern shown in Figure 3.4 can be described in complete detail using classical electromagnetic theory. The details of the interference pattern can be calculated with Maxwell’s equations. This and many other experiments, including the transmission of radio waves, can be described with classical theory. Therefore, classical theory, which treats light as a wave, appeared to be correct up to the beginning of the twentieth century. However, Chapter 4 shows how Einstein’s explanation of one phenomenon, the photoelectric effect, caused the beautiful and seemingly infallible edifice of classical electromagnetic theory to require fundamental rethinking.
4
The Photoelectric Effect and Einstein’s Explanation
AT THE END OF THE NINETEENTH CENTURY, classical electromagnetic theory was one of the great triumphs of classical mechanics. It was capable of explaining a wide variety of experimental observations. But early in the twentieth century, new experiments were causing problems for the classical wave picture of light. One experiment in particular, along with its explanation, showed a fundamental problem with the seemingly indestructible wave theory of light.
THE PHOTOELECTRIC EFFECT
The experiment is the observation of the photoelectric effect. In the photoelectric effect, light shines on a metal surface and, under the right conditions, electrons fly out of the metal. For our purposes here, electrons are electrically charged particles. The electron charge is negative. (Later we will see that electrons are not strictly particles for the same reason that light is not a wave.) Because electrons are charged particles, they are easy to detect. They can produce electrical signals in detection equipment. Figure 4.1 shows a schematic of the photoelectric effect with the incoming light viewed as a wave.
It is possible to measure the number of electrons that come out of the metal and their speed. For a particular metal and a given color of light, say blue, it is found that the electrons come out with a well-defined speed, and that the number of electrons that come out depends on the intensity of the light. If the intensity of light is increased, more electrons come out, but each electron has the same speed, independent of the intensity of the light. If the color of light is changed to red, the electron speed is slower, and if the color is made redder and redder, the electrons’ speed is slower and slower. For red enough light, electrons cease to come out of the metal.
THE WAVE PICTURE DOESN’T WORK
The problem for classical theory with these observations is that they are totally inconsistent with a wave picture of light. First, consider