Faraday As A Discoverer [18]
a jet of cold hydrogen. In his experiments on the decomposition of water, Faraday found that the positive platinum plate of the decomposing cell possessed in an extraordinary degree the power of causing oxygen and hydrogen to combine. He traced the cause of this to the perfect cleanness of the positive plate. Against it was liberated oxygen, which, with the powerful affinity of the 'nascent state,' swept away all impurity from the surface against which it was liberated. The bubbles of gas liberated on one of the platinum plates or wires of a decomposing cell are always much smaller, and they rise in much more rapid succession than those from the other. Knowing that oxygen is sixteen times heavier than hydrogen, I have more than once concluded, and, I fear, led others into the error of concluding, that the smaller and more quickly rising bubbles must belong to the lighter gas. The thing appeared so obvious that I did not give myself the trouble of looking at the battery, which would at once have told me the nature of the gas. But Faraday would never have been satisfied with a deduction if he could have reduced it to a fact. And he has taught me that the fact here is the direct reverse of what I supposed it to be. The small bubbles are oxygen, and their smallness is due to the perfect cleanness of the surface on which they are liberated. The hydrogen adhering to the other electrode swells into large bubbles, which rise in much slower succession; but when the current is reversed, the hydrogen is liberated upon the cleansed wire, and then its bubbles also become small. Footnotes to Chapter 5 [1] Buff finds the quantity of electricity associated with one milligramme of hydrogen in water to be equal to 45,480 charges of a Leyden jar, with a height of 480 millimetres, and a diameter of 160 millimetres. Weber and Kohlrausch have calculated that, if the quantity of electricity associated with one milligramme of hydrogen in water were diffused over a cloud at a height of 1000 metres above the earth, it would exert upon an equal quantity of the opposite electricity at the earth's surface an attractive force of 2,268,000 kilogrammes. (Electrolytische Maasbestimmungen, 1856, p. 262.) [2] Faraday, sa Vie et ses Travaux, p. 20. Chapter 6. Laws of electro-chemical decomposition. In our conceptions and reasonings regarding the forces of nature, we perpetually make use of symbols which, when they possess a high representative value, we dignify with the name of theories. Thus, prompted by certain analogies, we ascribe electrical phenomena to the action of a peculiar fluid, sometimes flowing, sometimes at rest. Such conceptions have their advantages and their disadvantages; they afford peaceful lodging to the intellect for a time, but they also circumscribe it, and by-and-by, when the mind has grown too large for its lodging, it often finds difficulty in breaking down the walls of what has become its prison instead of its home.[1] No man ever felt this tyranny of symbols more deeply than Faraday, and no man was ever more assiduous than he to liberate himself from them, and the terms which suggested them. Calling Dr. Whewell to his aid in 1833, he endeavoured to displace by others all terms tainted by a foregone conclusion. His paper on Electro-chemical Decomposition, received by the Royal Society on January 9, 1834, opens with the proposal of a new terminology. He would avoid the word 'current' if he could.[2] He does abandon the word 'poles' as applied to the ends of a decomposing cell, because it suggests the idea of attraction, substituting for it the perfectly natural term Electrodes. He applied the term Electrolyte to every substance which can be decomposed by the current, and the act of decomposition he called Electrolysis. All these terms have become current in science. He called the positive electrode the Anode, and the negative one the Cathode, but these terms, though frequently used, have not enjoyed the same currency as the others. The terms Anion and Cation, which he applied to the constituents of the decomposed