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Faraday As A Discoverer [21]

By Root 1231 0
as soon as these became known, suggestions and intimations appeared that chemical action, and not metallic contact, might be the real source of voltaic electricity. This idea was expressed by Fabroni in Italy, and by Wollaston in England. It was developed and maintained by those 'admirable electricians,' Becquerel, of Paris, and De la Rive, of Geneva. The Contact Theory, on the other hand, received its chief development and illustration in Germany. It was long the scientific creed of the great chemists and natural philosophers of that country, and to the present hour there may be some of them unable to liberate themselves from the fascination of their first-love. After the researches which I have endeavoured to place before you, it was impossible for Faraday to avoid taking a side in this controversy. He did so in a paper 'On the Electricity of the Voltaic Pile,' received by the Royal Society on the 7th of April, 1834. His position in the controversy might have been predicted. He saw chemical effects going hand in hand with electrical effects, the one being proportional to the other; and, in the paper now before us, he proved that when the former was excluded, the latter were sought for in vain. He produced a current without metallic contact; he discovered liquids which, though competent to transmit the feeblest currents--competent therefore to allow the electricity of contact to flow through them if it were able to form a current--were absolutely powerless when chemically inactive. One of the very few experimental mistakes of Faraday occurred in this investigation. He thought that with a single voltaic cell he had obtained the spark before the metals touched, but he subsequently discovered his error. To enable the voltaic spark to pass through air before the terminals of the battery were united, it was necessary to exalt the electro-motive force of the battery by multiplying its elements; but all the elements Faraday possessed were unequal to the task of urging the spark across the shortest measurable space of air. Nor, indeed, could the action of the battery, the different metals of which were in contact with each other, decide the point in question. Still, as regards the identity of electricities from various sources, it was at that day of great importance to determine whether or not the voltaic current could jump, as a spark, across an interval before contact. Faraday's friend, Mr. Gassiot, solved this problem. He erected a battery of 4000 cells, and with it urged a stream of sparks from terminal to terminal, when separated from each other by a measurable space of air. The memoir on the 'Electricity of the Voltaic Pile,' published in 1834, appears to have produced but little impression upon the supporters of the contact theory. These indeed were men of too great intellectual weight and insight lightly to take up, or lightly to abandon a theory. Faraday therefore resumed the attack in a paper, communicated to the Royal Society on the 6th of February, 1840. In this paper he hampered his antagonists by a crowd of adverse experiments. He hung difficulty after difficulty about the neck of the contact theory, until in its efforts to escape from his assaults it so changed its character as to become a thing totally different from the theory proposed by Volta. The more persistently it was defended, however, the more clearly did it show itself to be a congeries of devices, bearing the stamp of dialectic skill rather than of natural truth. In conclusion, Faraday brought to bear upon it an argument which, had its full weight and purport been understood at the time, would have instantly decided the controversy. 'The contact theory,' he urged, 'assumed that a force which is able to overcome powerful resistance, as for instance that of the conductors, good or bad, through which the current passes, and that again of the electrolytic action where bodies are decomposed by it, can arise out of nothing; that, without any change in the acting matter, or the consumption of any generating force, a current shall be produced
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