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Quantum_ Einstein, Bohr and the Great Debate About the Nature of Reality - Manjit Kumar [100]

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an atom was akin to a hypothetical oscillator that could produce all the frequencies of the spectrum. Max Planck had adopted a similar approach a quarter of a century earlier. However, while Planck had used brute force and ad hoc assumptions to generate a formula that he already knew to be correct, Heisenberg was being guided by the correspondence principle onto the familiar landscape of classical physics. Once it was set into motion, he could calculate properties of the oscillator such as its momentum p, the displacement from its equilibrium position q, and its frequency of oscillation. The spectral line with a frequency vmn would be emitted by one of a range of individual oscillators. Heisenberg knew that once he worked out the physics in this territory where the quantum and the classical met, he could extrapolate to explore the unknown interior of the atom.

Late one evening on Helgoland, all the pieces began falling into place. The theory built completely out of observables appeared to reproduce everything, but did it contravene the law of the conservation of energy? If it did, then it would collapse like a house of cards. Excited and nervous as he edged ever closer to proving that his theory was both physically and mathematically consistent, the 24-year-old physicist began making simple errors of arithmetic as he checked his calculations. It was almost three in the morning before Heisenberg could put down his pen, satisfied that the theory did not violate one of the most fundamental laws of physics. He was elated, but troubled. 'At first, I was deeply alarmed', Heisenberg recalled later.38 'I had the feeling that, through the surface of atomic phenomena, I was looking at a strangely beautiful interior, and felt almost giddy at the thought that I now had to probe this wealth of mathematical structures nature had so generously spread out before me.' Sleep was impossible – he was too excited. So as a new day dawned, Heisenberg walked to the southern tip of the island, where for days he had been longing to climb a rock jutting out into the sea. Fuelled by the adrenaline of discovery, he climbed it 'without too much trouble and waited for the Sun to rise'.39

In the cold light of day, Heisenberg's initial euphoria and optimism faded. His new physics appeared to work only with the help of a strange kind of multiplication where X times Y did not equal Y times X. With ordinary numbers it did not matter in which order they were multiplied: 4×5 gives exactly the same answer as 5×4, 20. Mathematicians called this property, where the ordering in multiplication is unimportant, commutation. Numbers obey the commutative law of multiplication, so (4×5)-(5×4) is always zero. It was a rule of mathematics that every child learned and Heisenberg was deeply troubled by the discovery that when he multiplied two arrays together, the answer was dependent on the order in which they were multiplied. (A×B)-(B×A) was not always zero.40

As the meaning of the peculiar multiplication he had been forced to use continued to elude him, on Friday, 19 June, Heisenberg travelled back to the mainland and headed straight to Hamburg and Wolfgang Pauli. A few hours later, having received words of encouragement from his severest critic, Heisenberg left for Göttingen and the task of refining and writing up what he had discovered. Only two days later, expecting to make quick progress, he wrote to Pauli that 'attempts to fabricate a quantum mechanics advance only slowly'.41 As the days passed, his frustration grew as he failed to apply his new approach to the hydrogen atom.

Whatever doubts he harboured, there was one thing Heisenberg was certain about. In any calculation, only relationships between 'observable' quantities, or those that could be measured in principle if not in reality, were permissible. He had given the observability of all quantities in his equations the status of a postulate and devoted his 'entire meagre efforts' to 'killing off and suitably replacing the concept of the orbital paths that one cannot observe'.42

'My own works are at the moment

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