Online Book Reader

Home Category

Quantum_ Einstein, Bohr and the Great Debate About the Nature of Reality - Manjit Kumar [14]

By Root 596 0
in 1882, 'ultimately it will have to be abandoned in favour of the assumption of continuous matter.'55 Eighteen years later, in the absence of indisputable proof of their existence, he still did not believe in atoms. Planck knew from the theory of electromagnetism that an electric charge oscillating at a certain frequency emits and absorbs radiation only of that frequency. He therefore chose to represent the walls of the blackbody as an enormous array of oscillators. Although each oscillator emits only a single frequency, collectively they emit the entire range of frequencies found within the blackbody.

A pendulum is an oscillator and its frequency is the number of swings per second, a single oscillation being one complete to and fro swing that returns the pendulum to its starting point. Another oscillator is a weight hanging from a spring. Its frequency is the number of times per second the weight bounces up and down after being pulled from its stationary position and released. The physics of such oscillations had long been understood and given the name 'simple harmonic motion' by the time Planck used oscillators, as he called them, in his theoretical model.

Planck envisaged his collection of oscillators as massless springs of varying stiffness, so as to reproduce the different frequencies, each with an electric charge attached. Heating the walls of the blackbody provided the energy needed to set the oscillators in motion. Whether an oscillator was active or not would depend only upon the temperature. If it were, then it would emit radiation into, and absorb radiation from, the cavity. In time, if the temperature is held constant, this dynamic give and take of radiation energy between the oscillators and the radiation in the cavity comes into balance and a state of thermal equilibrium is achieved.

Since the spectral energy distribution of blackbody radiation represents how the total energy is shared among the different frequencies, Planck assumed that it was the number of oscillators at each given frequency that determined the allocation. After setting up his hypothetical model, he had to devise a way to share out the available energy among the oscillators. In the weeks following its announcement, Planck discovered the hard way that he could not derive his formula using physics that he had long accepted as dogma. In desperation he turned to the ideas of an Austrian physicist, Ludwig Boltzmann, who was the foremost advocate of the atom. On the road to his blackbody formula, Planck became a convert as he accepted that atoms were more than just a convenient fiction, after years of being openly 'hostile to the atomic theory'.56

The son of a tax collector, Ludwig Boltzmann was short and stout with an impressive late nineteenth-century beard. Born in Vienna on 20February 1844, he was, for a while, taught the piano by the composer Anton Bruckner. A better physicist than a pianist, Boltzmann obtained his doctorate from the University of Vienna in 1866. He quickly made his reputation with fundamental contributions to the kinetic theory of gases, so called because its proponents believed that gases were made up of atoms or molecules in a state of continual motion. Later, in 1884, Boltzmann provided the theoretical justification for the discovery by Josef Stefan, his former mentor, that the total energy radiated by a blackbody is proportional to the temperature raised to the fourth power, T4 or T×T×T×T. It meant that doubling the temperature of a blackbody increased the energy it radiated by a factor of sixteen.

Boltzmann was a renowned teacher and, although a theorist, a very capable experimentalist despite being severely shortsighted. Whenever a vacancy arose at one of Europe's leading universities his name was usually on the list of potential candidates. It was only after he turned down the professorship at Berlin University left vacant by the death of Gustav Kirchhoff that a downgraded version was offered to Planck. By 1900 a much-travelled Boltzmann was at Leipzig University and universally acknowledged as one the great

Return Main Page Previous Page Next Page

®Online Book Reader