Quantum_ Einstein, Bohr and the Great Debate About the Nature of Reality - Manjit Kumar [33]
Hertz proclaimed in his paper outlining his investigations: 'The experiments described appear to me, at any rate, eminently adapted to remove any doubt as to the identity of light, radiant heat, and electromagnetic wave motion. I believe that from now on we shall have greater confidence in making use of the advantages, which this identity enables us to derive both in the study of optics and electricity.'72 Ironically, it was during these very experiments that Hertz discovered the photoelectric effect that provided Einstein with evidence for a case of mistaken identity. His light-quanta challenged the wave theory of light that Hertz and everyone else thought was well and truly established. Light as a form of electromagnetic radiation had proved so successful that for physicists to even contemplate discarding it in favour of Einstein's light-quanta was unthinkable. Many found light-quanta absurd. After all, the energy of a particular quantum of light was determined by the frequency of that light, but surely frequency was something associated with waves, not particle-like bits of energy travelling through space.
Einstein readily accepted that the wave theory of light had 'proved itself superbly' in explaining diffraction, interference, reflection and refraction, and that it would 'probably never be replaced by another theory'.73 However, this success, he pointed out, rested on the vital fact that all these optical phenomena involved the behaviour of light over a period of time, and any particle-like properties would not be manifest. The situation was starkly different when it came to the virtually 'instantaneous' emission and absorption of light. This was the reason, Einstein suggested, why the wave theory faced 'especially great difficulties' explaining the photoelectric effect.74
A future Nobel laureate, but in 1906 a privatdozent at Berlin University, Max Laue wrote to Einstein that he was willing to accept that quanta may be involved during the emission and absorption of light. However, that was all. Light itself was not made up of quanta, warned Laue, but it is 'when it is exchanging energy with matter that it behaves as if it consisted of them'.75 Few even conceded that much. Part of the problem lay with Einstein himself. In his original paper he did say that light 'behaves' as though it consisted of quanta. This was hardly a categorical endorsement of the quantum of light. This was because Einstein wanted something more than just a 'heuristic point of view': he craved a fully-fledged theory.
The photoelectric effect had proved to be a battlefield for the clash between the supposed continuity of light waves and the discontinuity of matter, atoms. But in 1905 there were still those who doubted the reality of atoms. On 11 May, less than two months after he finished his quantum paper, the Annalen der Physik received Einstein's second paper of the year. It was his explanation of Brownian motion and it became a key piece of evidence in support of the existence of atoms.76
When in 1827 the Scottish botanist Robert Brown peered through a microscope at some pollen grains suspended in water, he saw that they were in a constant state of haphazard motion as if buffeted by some unseen force. It had already been noted by others that this erratic wiggling increased as the temperature of the water rose, and it was assumed that some sort of biological