The History and Practice of the Art of Photography [13]
and then again a fine yellow circle, centred by a greyish spot on the place occupied by the iodine. On exposing these to the light, the outer yellow circle almost instantly changes color, the others slowly, in the order of their position, the interior yellow circle resisting for a long time the solar influence. These rings must be regarded as films of the ioduret of silver, varying, not only in thickness, but in the more or less perfect states of combination in which the iodine and metal are. The exterior circle is an ioduret in a very loose state of chemical agregation; the attractive forces increase as we proceed towards the centre, where a well formed ioduret, or probably a true iodide of silver, is formed, which is acted upon by sunlight with difficulty. The exterior and most sensitive film constitutes the surface of Daguerreotype plates. The changes which these colored rings undergo are remarkable; by a few minutes exposure to sunlight, an inversion of nearly all the colors takes place, the two first rings becoming a deep olive green; and a deep blue inclining to black.
The nature of the change which the ioduret of silver undergoes on Daguerreotype plates, through the action of light, Mr. Hunt considers to be a decided case of decomposition, and cites several circumstances in proof of his position. These with other facts given by Mr. Hunt in his great work on the Photographic art, but to volumnious to include in a volume of the size to which I am obliged to cofine myself, should be thoroughly studied by all Daguerreotypists.
PRISMATIC ANALYSIS.--The most refrangible portion of the spectrum, (on a Daguerreotype plate) appears, after the plate has been exposed to the vapor of mercury, to have impressed its colors; the light and delicate film of mercury, which covers that portion, assuming a fine blue tint about the central parts, which are gradually shaded off into a pale grey; and this is again surrounded by a very delicate rose hue, which is lost in a band of pure white. Beyond this a protecting influence is powerfully exerted; and notwithstanding the action of the dispersed light, which is very evident over the plate, a line is left, perfectly free from mercurial vapor, and which, consequently, when viewed by a side light, appears quite dark. The green rays are represented by a line of a corresponding tint, considerably less in size than the luminous green rays. The yellow rays appear to be without action, or to act negatively, the space upon which they fall being protected from the mercurial vapor; and it consequently is seen as a dark band. A white line of vapor marks the place of the orange rays. The red rays effect the sensitive surface in a peculiar manner; and we have the mercurial vapor, assuming a molecular arrangement which gives to it a fine rose hue; this tint is surrounded by a line of white vapor, shaded at the lowest extremity with a very soft green. Over the space occupied by the extreme red rays, a protecting influence is again exerted; the space is retained free from mercurial vapor and the band is found to surround the whole of the least refrangible rays, and to unite itself with the band which surrounds the rays of greatest refrangibility. This band is not equally well defined throughout its whole extent. It is most evident from the extreme red to the green; it fades in passing through the blue, and increases again, as it leaves the indigo, until beyond the invisible chemical rays it is nearly as strong as it is at the calorific end of the spectrum.
Images on Daguerreotype plates which have been completely obliterated by rubbing may be restored, by placing it in a tolerably strong solution of iodine in water.
BROMIDE OF SILVER.--This salt, like the iodide, does not appear to be readily changed by the action of light; but when combined with the nitrate of silver it forms a very sensitive photographic preparation.
Paper prepared with this salt, blackens over its whole extent with nearly equal intensity, when submitted to the prismatic spectrum. The most characteristic peculiarity
The nature of the change which the ioduret of silver undergoes on Daguerreotype plates, through the action of light, Mr. Hunt considers to be a decided case of decomposition, and cites several circumstances in proof of his position. These with other facts given by Mr. Hunt in his great work on the Photographic art, but to volumnious to include in a volume of the size to which I am obliged to cofine myself, should be thoroughly studied by all Daguerreotypists.
PRISMATIC ANALYSIS.--The most refrangible portion of the spectrum, (on a Daguerreotype plate) appears, after the plate has been exposed to the vapor of mercury, to have impressed its colors; the light and delicate film of mercury, which covers that portion, assuming a fine blue tint about the central parts, which are gradually shaded off into a pale grey; and this is again surrounded by a very delicate rose hue, which is lost in a band of pure white. Beyond this a protecting influence is powerfully exerted; and notwithstanding the action of the dispersed light, which is very evident over the plate, a line is left, perfectly free from mercurial vapor, and which, consequently, when viewed by a side light, appears quite dark. The green rays are represented by a line of a corresponding tint, considerably less in size than the luminous green rays. The yellow rays appear to be without action, or to act negatively, the space upon which they fall being protected from the mercurial vapor; and it consequently is seen as a dark band. A white line of vapor marks the place of the orange rays. The red rays effect the sensitive surface in a peculiar manner; and we have the mercurial vapor, assuming a molecular arrangement which gives to it a fine rose hue; this tint is surrounded by a line of white vapor, shaded at the lowest extremity with a very soft green. Over the space occupied by the extreme red rays, a protecting influence is again exerted; the space is retained free from mercurial vapor and the band is found to surround the whole of the least refrangible rays, and to unite itself with the band which surrounds the rays of greatest refrangibility. This band is not equally well defined throughout its whole extent. It is most evident from the extreme red to the green; it fades in passing through the blue, and increases again, as it leaves the indigo, until beyond the invisible chemical rays it is nearly as strong as it is at the calorific end of the spectrum.
Images on Daguerreotype plates which have been completely obliterated by rubbing may be restored, by placing it in a tolerably strong solution of iodine in water.
BROMIDE OF SILVER.--This salt, like the iodide, does not appear to be readily changed by the action of light; but when combined with the nitrate of silver it forms a very sensitive photographic preparation.
Paper prepared with this salt, blackens over its whole extent with nearly equal intensity, when submitted to the prismatic spectrum. The most characteristic peculiarity