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The Quantum Universe_ Everything That Can Happen Does Happen - Brian Cox [74]

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At room temperature they can carry a current of electricity, but as they are cooled down, and their atoms jiggle less, so their ability to conduct electricity diminishes and they turn back into insulators. Silicon and germanium are the two classic examples of semiconductor materials and, because of their dual nature, they can be used to great advantage. Indeed, it is no exaggeration to say that the technological application of semiconductor materials revolutionized the world.

9. The Modern World


In 1947, the world’s first transistor was built. Today, every year the world manufactures over 10,000,000,000,000,000,000, which is one hundred times more than the sum total of all the grains of rice consumed every year by the world’s seven billion residents. The world’s first transistor computer was built in Manchester in 1953, and had ninety-two of them. Today, you can buy over a hundred thousand transistors for the cost of a single grain of rice and there are around a billion of them in your mobile phone. In this chapter, we are going to describe how a transistor works, surely the most important application of quantum theory.

As we saw in the previous chapter, a conductor is a conductor because some of the electrons are sitting in the conduction band. As a result, they are quite mobile and can ‘flow down’ the wire when a battery is connected. The analogy with flowing water is a good one; the battery is causing current to flow. We can even use the ‘potential’ concept to capture this idea, because the battery creates a potential within which the conduction electrons move, and the potential is in a sense, ‘downhill’. So an electron in the conduction band of a material ‘rolls’ down the potential created by the battery, gaining energy as it goes. This is another way to think about the tiny kicks we talked about in the last chapter – instead of a battery inducing tiny kicks that accelerate the electron along the wire, we are invoking a classical analogy akin to water flowing down a hill. This is a good way to think about the conduction of electricity by electrons, and it is the way we will be thinking throughout the rest of this chapter.

In a semiconductor material like silicon, something very interesting happens because the current is not only carried by electrons in the conduction band. The electrons in the valence band contribute to the current too. To see that, take a look at Figure 9.1. The arrow shows an electron, originally sitting inert in the valence band, absorbing some energy and being lifted up into the conduction band. Certainly the elevated electron is now much more mobile, but something else is mobile too – there is now a hole left in the valence band, and that hole provides some wriggle room for the otherwise inert valence band electrons. As we have seen, connecting a battery to this semiconductor will cause the conduction band electron to hop up in energy, thereby inducing an electric current. What happens to that hole? The electric field created by the battery can cause an electron from some lower energy state in the valence band to hop into the vacant hole. The hole is filled in, but now there is a hole ‘deeper’ down in the valence band. When electrons in the valence band hop into the vacant hole, the hole moves around.

Figure 9.1. An electron-hole pair in a semiconductor.

Rather than bother keeping track of the motion of all the electrons in the almost-full valence band, we can instead decide to keep track of where the hole is and forget about the electrons. That book-keeping convenience is the norm for those working on the physics of semiconductors, and it will make our life simpler to think in that way too.

An applied electric field induces the conduction band electrons to flow, creating a current, and we should like to know what it does to the holes in the valence band. We know that the valence band electrons are not free to move, because they are almost completely trapped by the Pauli principle but they will shuffle along under the influence of the electric field and the hole moves along with

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