Darwin and Modern Science [388]
strontium compared with that of hydrogen as unity, is about the mean of those of calcium (40) and barium (137). Such relations, in this and other chemical groups, were illustrated by Beguyer de Chancourtois in 1862 by the construction of a spiral diagram in which the atomic weights are placed in order round a cylinder and elements chemically similar are found to fall on vertical lines.
Newlands seems to have been the first to see the significance of such a diagram. In his "law of octaves," formulated in 1864, he advanced the hypothesis that, if arranged in order of rising atomic weight, the elements fell into groups, so that each eighth element was chemically similar. Stated thus, the law was too definite; no room was left for newly- discovered elements, and some dissimilar elements were perforce grouped together.
But in 1869 Mendeleeff developed Newland's hypothesis in a form that attracted at once general attention. Placing the elements in order of rising atomic weight, but leaving a gap where necessary to bring similar elements into vertical columns, he obtained a periodic table with natural vacancies to be filled as new elements were discovered, and with a certain amount of flexibility at the ends of the horizontal lines. From the position of the vacancies, the general chemical and physical properties of undiscovered elements could be predicted, and the success of such predictions gave a striking proof of the usefulness of Mendeleeff's generalisation.
When the chemical and physical properties of the elements were known to be periodic functions of their atomic weights, the idea of a common origin and common substance became much more credible. Differences in atomic weight and differences in properties alike might reasonably be explained by the differences in the amount of the primordial substance present in the various atoms; an atom of oxygen being supposed to be composed of sixteen times as much stuff as the atom of hydrogen, but to be made of the same ultimate material. Speculations about the mode of origin of the elements now began to appear, and put on a certain air of reality. Of these speculations perhaps the most detailed was that of Crookes, who imagined an initial chaos of a primordial medium he named protyle, and a process of periodic change in which the chemical elements successively were precipitated.
From another side too, suggestions were put forward by Sir Norman Lockyer and others that the differences in spectra observed in different classes of stars, and produced by different conditions in the laboratory, were to be explained by changes in the structure of the vibrating atoms.
The next step in advance gave a theoretical basis for the idea of a common structure of matter, and was taken in an unexpected direction. Clerk Maxwell's electromagnetic theory of light, accepted in England, was driven home to continental minds by the confirmatory experiments of Hertz, who in 1888 detected and measured the electromagnetic waves that Maxwell had described twenty years earlier. But, if light be an electromagnetic phenomenon, the light waves radiated by hot bodies must take their origin in the vibrations of electric systems. Hence within the atoms must exist electric charges capable of vibration. On these lines Lorentz and Larmor have developed an electronic theory of matter, which is imagined in its essence to be a conglomerate of electric charges, with electro-magnetic inertia to explain mechanical inertia. (Larmor, "Aether and Matter", Cambridge, 1900.) The movement of electric charges would be affected by a magnetic field, and hence the discovery by Zeeman that the spectral lines of sodium were doubled by a strong magnetic force gave confirmatory evidence to the theory of electrons.
Then came J.J. Thomson's great discovery of minute particles, much smaller than any chemical atom, forming a common constituent of many different kinds of matter. (Thomson, "Conduction of Electricity through Gases" (2nd edition), Cambridge, 1906.) If an electric discharge be passed between metallic
Newlands seems to have been the first to see the significance of such a diagram. In his "law of octaves," formulated in 1864, he advanced the hypothesis that, if arranged in order of rising atomic weight, the elements fell into groups, so that each eighth element was chemically similar. Stated thus, the law was too definite; no room was left for newly- discovered elements, and some dissimilar elements were perforce grouped together.
But in 1869 Mendeleeff developed Newland's hypothesis in a form that attracted at once general attention. Placing the elements in order of rising atomic weight, but leaving a gap where necessary to bring similar elements into vertical columns, he obtained a periodic table with natural vacancies to be filled as new elements were discovered, and with a certain amount of flexibility at the ends of the horizontal lines. From the position of the vacancies, the general chemical and physical properties of undiscovered elements could be predicted, and the success of such predictions gave a striking proof of the usefulness of Mendeleeff's generalisation.
When the chemical and physical properties of the elements were known to be periodic functions of their atomic weights, the idea of a common origin and common substance became much more credible. Differences in atomic weight and differences in properties alike might reasonably be explained by the differences in the amount of the primordial substance present in the various atoms; an atom of oxygen being supposed to be composed of sixteen times as much stuff as the atom of hydrogen, but to be made of the same ultimate material. Speculations about the mode of origin of the elements now began to appear, and put on a certain air of reality. Of these speculations perhaps the most detailed was that of Crookes, who imagined an initial chaos of a primordial medium he named protyle, and a process of periodic change in which the chemical elements successively were precipitated.
From another side too, suggestions were put forward by Sir Norman Lockyer and others that the differences in spectra observed in different classes of stars, and produced by different conditions in the laboratory, were to be explained by changes in the structure of the vibrating atoms.
The next step in advance gave a theoretical basis for the idea of a common structure of matter, and was taken in an unexpected direction. Clerk Maxwell's electromagnetic theory of light, accepted in England, was driven home to continental minds by the confirmatory experiments of Hertz, who in 1888 detected and measured the electromagnetic waves that Maxwell had described twenty years earlier. But, if light be an electromagnetic phenomenon, the light waves radiated by hot bodies must take their origin in the vibrations of electric systems. Hence within the atoms must exist electric charges capable of vibration. On these lines Lorentz and Larmor have developed an electronic theory of matter, which is imagined in its essence to be a conglomerate of electric charges, with electro-magnetic inertia to explain mechanical inertia. (Larmor, "Aether and Matter", Cambridge, 1900.) The movement of electric charges would be affected by a magnetic field, and hence the discovery by Zeeman that the spectral lines of sodium were doubled by a strong magnetic force gave confirmatory evidence to the theory of electrons.
Then came J.J. Thomson's great discovery of minute particles, much smaller than any chemical atom, forming a common constituent of many different kinds of matter. (Thomson, "Conduction of Electricity through Gases" (2nd edition), Cambridge, 1906.) If an electric discharge be passed between metallic