Genius_ The Life and Science of Richard Feynman - James Gleick [22]
Not solids but gases began to persuade seventeenth- and eighteenth-century scientists of matter’s fundamental granularity. In the heady aftermath of Newton’s revolution scientists made measurements, found constant quantities, and forged mathematical relationships that a philosophy without numbers had left hidden. Investigators made and unmade water, ammonia, carbonic acid, potash, and dozens of other compounds. When they carefully weighed the ingredients and end products, they discovered regularities. Volumes of hydrogen and oxygen vanished in a neat two-to-one ratio in the making of water. Robert Boyle found in England that, although one could vary both the pressure and the volume of air trapped at a given temperature in a piston, one could not vary their product. Pressure multiplied by volume was a constant. These measures were joined by an invisible rod—why? Heating a gas increased its volume or its pressure. Why?
Heat had seemed to flow from one place to another as an invisible fluid—“phlogiston” or “caloric.” But a succession of natural philosophers hit on a less intuitive idea—that heat was motion. It was a brave thought, because no one could see the things in motion. A scientist had to imagine uncountable corpuscles banging invisibly this way and that in the soft pressure of wind against his face. The arithmetic bore out the guess. In Switzerland Daniel Bernoulli derived Boyle’s law by supposing that pressure was precisely the force of repeated impacts of spherical corpuscles, and in the same way, assuming that heat was an intensification of the motion hither and thither, he derived a link between temperature and density. The corpuscularians advanced again when Antoine-Laurent Lavoisier, again with painstaking care, demonstrated that one could keep reliable account books of the molecules entering and exiting any chemical reaction, even when gases joined with solids, as in rusting iron.
“Matter is unchangeable, and consists of points that are perfectly simple, indivisible, of no extent”—that the atom could itself contain a crowded and measurable universe remained for a later century to guess—“& separated from one another.” Ruggiero Boscovich, an eighteenth-century mathematician and director of optics for the French navy, developed a view of atoms with a strikingly prescient bearing, a view that Feynman’s single-sentence credo echoed two centuries later. Boscovich